Serpentinization-Driven H2 Production From Continental Break-Up to Mid-Ocean Ridge Spreading: Unexpected High Rates at the West Iberia Margin

Molecular hydrogen (H2) released during serpentinization of mantle rocks is one of the main fuels for chemosynthetic life. Processes of H2 production at slow-spreading mid-ocean ridges (MORs) have received much attention in the past. Less well understood is serpentinization at passive continental margins where different rock types are involved (lherzolite instead of harzburgite/dunite at MORs) and the alteration temperatures tend to be lower (<200°C vs. >200°C). To help closing this knowledge gap we investigated drill core samples from the West Iberia margin. Lherzolitic compositions and spinel geochemistry indicate that the exhumed peridotites resemble sub-continental lithospheric mantle. The rocks are strongly serpentinized, mainly consist of serpentine with little magnetite, and are generally brucite-free. Serpentine can be uncommonly Fe-rich, with XMg = Mg/(Mg + Fe) < 0.8, and shows distinct compositional trends toward a cronstedtite endmember. Bulk rock and silicate fraction Fe(III)/∑Fe ratios are 0.6–0.92 and 0.58–0.8, respectively; our data show that 2/3 of the ferric Fe is accounted for by Fe(III)-serpentine. Mass balance and thermodynamic calculations suggest that the sample’s initial serpentinization produced ∼120 to >300 mmol H2 per kg rock. The cold, late-stage weathering of the serpentinites at the seafloor caused additional H2 formation. These results suggest that the H2 generation potential evolves during the transition from continental break-up to ultraslow and, eventually, slow MOR spreading. Metamorphic phase assemblages systematically vary between these settings, which has consequences for H2 yields during serpentinization. At magma-poor rifted margins and ultraslow-spreading MORs, serpentine hosts most Fe(III). Hydrogen yields of 120 to >300 mmol and 50–150 mmol H2 per kg rock, respectively, may be expected at temperatures of <200°C. At slow-spreading MORs, in contrast, serpentinization may produce 200–350 mmol H2, most of which is related to magnetite formation at >200°C. Since, in comparison to slow-spreading MORs, geothermal gradients at magma-poor margins and ultraslow-spreading MORs are lower, larger volumes of low-temperature serpentinite should form in these settings. Serpentinization of lherzolitic rocks at magma-poor margins should produce particularly high amounts of H2 under conditions within the habitable zone. Magma-poor margins may hence be more relevant environments for hydrogenotrophic microbial life than previously thought

Astronomical calibration of the Ypresian timescale: implications for seafloor spreading rates and the chaotic behavior of the solar system?

Abstract. To fully understand the global climate dynamics of the warm early Eocene with its reoccurring hyperthermal events, an accurate high-fidelity age model is required. The Ypresian stage (56–47.8 Ma) covers a key interval within the Eocene as it ranges from the warmest marine temperatures in the early Eocene to the long-term cooling trends in the middle Eocene. Despite the recent development of detailed marine isotope records spanning portions of the Ypresian stage, key records to establish a complete astronomically calibrated age model for the Ypresian are still missing. Here we present new high-resolution X-ray fluorescence (XRF) core scanning iron intensity, bulk stable isotope, calcareous nannofossil, and magnetostratigraphic data generated on core material from ODP Sites 1258 (Leg 207, Demerara Rise), 1262, 1263, 1265, and 1267 (Leg 208, Walvis Ridge) recovered in the equatorial and South Atlantic Ocean. By combining new data with published records, a 405 kyr eccentricity cyclostratigraphic framework was established, revealing a 300–400 kyr long condensed interval for magnetochron C22n in the Leg 208 succession. Because the amplitudes are dominated by eccentricity, the XRF data help to identify the most suitable orbital solution for astronomical tuning of the Ypresian. Our new records fit best with the La2010b numerical solution for eccentricity, which was used as a target curve for compiling the Ypresian astronomical timescale (YATS). The consistent positions of the very long eccentricity minima in the geological data and the La2010b solution suggest that the macroscopic feature displaying the chaotic diffusion of the planetary orbits, the transition from libration to circulation in the combination of angles in the precession motion of the orbits of Earth and Mars, occurred  ∼  52 Ma. This adds to the geological evidence for the chaotic behavior of the solar system. Additionally, the new astrochronology and revised magnetostratigraphy provide robust ages and durations for Chrons C21n to C24n (47–54 Ma), revealing a major change in spreading rates in the interval from 51.0 to 52.5 Ma. This major change in spreading rates is synchronous with a global reorganization of the plate–mantle system and the chaotic diffusion of the planetary orbits. The newly provided YATS also includes new absolute ages for biostratigraphic events, magnetic polarity reversals, and early Eocene hyperthermal events. Our new bio- and magnetostratigraphically calibrated stable isotope compilation may act as a reference for further paleoclimate studies of the Ypresian, which is of special interest because of the outgoing warming and increasingly cooling phase. Finally, our approach of integrating the complex comprehensive data sets unearths some challenges and uncertainties but also validates the high potential of chemostratigraphy, magnetostratigraphy, and biostratigraphy in unprecedented detail being most significant for an accurate chronostratigraphy

A New Grounding-line Proximal Sedimentary Record from Inner Pine Island Bay

Pine Island Glacier (PIG) is one of the fastest changing ice streams of the West Antarctic Ice Sheet. Its ice shelf underwent major calving events throughout recent years. The main factor for the considerable mass loss of PIG is sub-ice shelf melting caused by the advection of warm deep water into Pine Island Bay on the shelf of the southeastern Amundsen Sea Embayment (ASE). Unique ice conditions during expedition PS104 with RV “Polarstern” to the ASE in February-March 2017 allowed to recover a 7.59 m-gravity core in an area that had been covered by the PIG ice shelf until 2015. The sediment core PS104_008-2 was taken at a water depth of 698 m near the eastern margin of the ice shelf. The new sedimentological data from the core will provide insights into sub-ice shelf environmental conditions and the Holocene history of meltwater plume deposition and oceanic ice-shelf melting. We will present results of our new multi-proxy study, including down-core lithological changes, grain size distribution and excess 210Pb data. Occasional occurrence of calcareous benthic foraminifera shells in the lower part of the core will allow the application of radiocarbon dating. Coupled with the excess 210Pb data, the AMS 14C ages will provide constraints on sub-ice shelf sediment accumulation rates and the discharge rates of subglacial meltwater plumes

Dating North Pacific Abyssal Sediments by Geomagnetic Paleointensity: Implications of Magnetization Carriers, Plio-Pleistocene Climate Change, and Benthic Redox Conditions

Non-carbonaceous abyssal fine-grained sediments cover vast parts of the North Pacific’s deep oceanic basins and gain increasing interests as glacial carbon traps. They are, however, difficult to date at an orbital-scale temporal resolution and still rarely used for paleoceanographic reconstructions. Here, we show that sedimentary records of past geomagnetic field intensity have high potential to improve reversal-based magnetostratigraphic age models. Five sediment cores from Central North Pacific mid-latitudes (39–47°N) and abyssal water depths ranging from 3,900 to 6,100 m were cube-sampled at 23 mm resolution and analyzed by automated standard paleo- and rock magnetic methods, XRF scanning, and electron microscopy. Relative Paleointensity (RPI) records were determined by comparing natural vs. anhysteretic remanent magnetization losses during alternating field demagnetization using a slope method within optimized coercivity windows. The paleomagnetic record delivered well interpretable geomagnetic reversal sequences back to 3 Ma. This age span covers the climate-induced transition from a biogenic magnetite prevalence in the Late Pliocene and Early Pleistocene to a dust-dominated detrital magnetic mineral assemblage since the Mid-Pleistocene. Volcaniclastic materials from concurrent eruptions and gravitational or contouritic sediment re-deposition along extinct seamount flanks provide a further important source of fine- to coarse-grained magnetic carriers. Surprisingly, higher proportions of biogenic vs. detrital magnetite in the late Pliocene correlate with systematically lowered RPI values, which seems to be a consequence of magnetofossil oxidation rather than reductive depletion. Our abyssal RPI records match the astronomically tuned stack of the mostly bathyal Pacific RPI records. While a stratigraphic correlation of rock magnetic and element ratio logs with standard oxygen isotope records was sporadically possible, the RPI minima allowed to establish further stratigraphic tie points at ∼50 kyr intervals. Thus, this RPI-enhanced magnetostratigraphy appears to be a major step forward to reliably date unaltered abyssal North Pacific sediments close to orbital-scale resolution

Synchronizing the timing of anoxia, volcanism and the pacing of the Earth’s orbit in the Early Cretaceous

Recurrent acceleration of the hydrolysing cycle, so-called Episodes of Environmental Changes, occur in the Early Cretaceous. As the geologic time scale show large uncertainties, the pacing and the chronological relationship of these events remain obscure. We present here new radio-astrochronologic data from the Neuquén Basin (Argentina) anchored to the Tethyan realm. The new time sale of the Valanginian-Hauterivian provides ages of ammonite zones with an uncertainty of ± 0.2 myr and provides much precise age of the start of the Weissert Event. The age of the start of the Weissert Event is at 134.5 ± 0.2 myr, which is exactly synchronous with the main phase of the Paraná-Etendeka large igneous province activity. Most recent duration and age estimates from the Berriasian to the Barremian are reviewed and differ from the Geologic Time Scale 2016 by several million of years. Thanks to this new time scale, belemnite δ13C are reviewed and show a strong pacing with a period of 2.4 myr, which correspond to the long-eccentricity cycle. Higher amplitudes of the 2.4-myr cycle are observed at time of large igneous province emplacement, which may be due to accelerated hydrolysis cycle following CO2 input to the atmosphere from the volcanic activity.Fil: Martinez, Mathieu. Universite de Rennes I; FranciaFil: Aguirre Urreta, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Lescano, Marina Aurora. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Omarini, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación en Paleobiología y Geología; ArgentinaFil: Tunik, Maisa Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación en Paleobiología y Geología; ArgentinaFil: Frederichs, Thomas. Universitat Bremen; AlemaniaFil: Nickl, Anna-Leah. Universitat Bremen; AlemaniaFil: Pälike, Heiko. Universitat Bremen; AlemaniaEGU General Assembly 2019VienaAustriaEuropean Geosciences Unio

Evidence for a palaeo-subglacial lake on the Antarctic continental shelf

Subglacial lakes are widespread beneath the Antarctic Ice Sheet but their control on ice-sheet dynamics and their ability to harbour life remain poorly characterized. Here we present evidence for a palaeo-subglacial lake on the Antarctic continental shelf. A distinct sediment facies recovered from a bedrock basin in Pine Island Bay indicates deposition within a low-energy lake environment. Diffusive-advection modelling demonstrates that low chloride concentrations in the pore water of the corresponding sediments can only be explained by initial deposition of this facies in a freshwater setting. These observations indicate that an active subglacial meltwater network, similar to that observed beneath the extant ice sheet, was also active during the last glacial period. It also provides a new framework for refining the exploration of these unique environments

Arctic Ocean evidence for late Quaternary initiation of northern Eurasian ice sheets

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets

Arctic Ocean evidence for late Quaternary initiation of northern Eurasian ice sheets

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets

Interplay between detrital and diagenetic processes since the last glacial maximum on the northwest Iberian continental shelf

Author Posting. © The Author(s), 2010. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Quaternary Research 73 (2010): 507-520, doi:10.1016/j.yqres.2010.02.003.Integrated analyses of magnetic, geochemical and textural data on six cores from the northwestern Iberian continental shelf allowed the reconstruction of the paleoenvironmental evolution of this area since the last glacial maximum (LGM). Four sedimentary units were identified, representing a succession from fluvial and subaerial settings to high and finally low-energy marine deposits subsequent to the post-LGM sea evel rise. The uppermost unit was deposited during the Holocene and its magnetic properties were controlled by the interplay between detrital input and early diagenetic reductive dissolution of magnetic minerals. Identification of a primary steady-state early diagenetic signal allowed the recognition of periods of increased detrital input bounded by intervals of lower detrital input and intensified reductive diagenesis related related to upwelling intensifications in the area. These paleoenvironmental alternations are consistent with the climatic evolution of the late Holocene. During the Roman Warm Period (RWP) and Medieval Warm Period (MWP), the combined effect of greater humidity and intense agricultural and mining activities led to a greater erosion and transport of detrital sediments to the shelf. In contrast, enhanced diagenetic reduction intervals, caused by upwelling intensification, were roughly coincident with the colder Dark Ages (DA) and the Little Ice Age (LIA).Contribution to projects CTM2007-61227/MAR and REN2003-02822 funded by the Spanish MICINN. Partial contribution to projects PGIDIT06TAM31201PR and IN825B funded by Xunta de Galicia and NACSA 236962 and ANCORIM funded by the EU. The EU Paleostudies program funded the stay of Kais J. Mohamed in Bremen. K. J. Mohamed wishes to acknowledge joint funding from the Fulbright Program and the Spanish Ministry of Education and Science and the Marie Curie International Outgoing Fellowships within the 7th European Community Framework Programme

Sedimentation rates in the Makarov Basin, central Arctic Ocean: A paleomagnetic and rock magnetic approach

Three long sediment cores from the Makarov Basin have been subjected to detailed paleomagnetic and rock magnetic analyses. Investigated sediments are dominated by normal polarity including short reversal excursions, indicating that most of the sediments are of Brunhes age. In general, the recovered sediments show only low to moderate variability in concentration and grain size of the remanence-carrying minerals. Estimations of relative paleointensity variations yielded a well-documented succession of pronounced lows and highs that could be correlated to published reference curves. However, together with five accelerator mass spectrometry C-14 ages and an incomplete Be-10 record, still two different interpretations of the paleomagnetic data are possible, with long-term sedimentation rates of either 1.3 or 4 cm kyr(-1) However, both models implicate highly variable sedimentation rates of up to 10 cm kyr(-1), and abrupt changes in rock magnetic parameters might even indicate several hiatuses